Earth's atmosphere has a lot of oxygen because life has been producing it for billions of years. Oxygen isn't stable enough to last long on its own, so it must be constantly produced in order to be so abundant.
The combination of carbon dioxide and methane (like in Earth's atmosphere) is even more telling, especially if there's no carbon monoxide.
That's because carbon dioxide and methane would normally react with each other to produce new compounds. So if they exist separately, something is probably constantly producing them. That something could be a volcano, but as far as we know, only a lifeform could release that much methane without also belching out carbon monoxide.